New 2D material with super-heavy electrons

A new 2D quantum material has been discovered. The material consists of atom-thin layers of cerium, silicon and iodine (CeSiI) and is the first example of a 2D material with heavy fermions. It is presented in a new study by researchers in materials science at Uppsala University and others, published in the scientific journal Nature.

Peer-review/Computational simulation/modelling and Experimental study

“The electrons in CeSiI behave as if they have up to 100 times more mass than electrons in ordinary materials. This is why they are called heavy fermions. What is extra special about CeSiI is that this effective mass is anisotropic, that it depends on the direction in which the electrons move in the atomic layers,” says Chin Shen Ong, one of the Uppsala researchers behind the study.

The research is a collaboration between researchers in materials theory at Uppsala University and researchers at Columbia University in the United States. For the materials researchers from Uppsala University, the main issue was to theoretically investigate the quantum properties of electrons in the material.

Heavy fermion compounds are a class of materials in which the electrons interact with each other unusually strongly. In so doing, they coordinate their movements in so-called quantum fluctuations. This interaction causes the electrons to behave as if they had up to 100 or 1,000 times more mass than electrons in ordinary materials. These quantum fluctuations are thought to play an important role in a number of hitherto unexplained quantum phenomena, such as unconventional superconductivity, where an electric current can pass through a material without loss of energy, and magnetism.

Research on materials with heavy fermions has been going on for decades, but until now the focus has been on materials where the atoms are tightly packed in a 3D structure. As far back as the 1970s, researchers at Uppsala University focused on cerium-based materials, with great success.

However, the new material, synthesised in the Columbia University laboratory, is unique as it has a 2D-like crystal structure with clearly separated, atom-thin layers. The layers consist of cerium, silicon and iodine (CeSiI) and are the first example of a 2D material with heavy fermions.

“With this discovery, we now have a significantly improved material platform for investigating correlated electron structures. 2D materials are like a construction kit with LEGO pieces. Our partners are already working on adding layers from other 2D materials to create a new material with customised quantum properties,” says Chin Shen Ong.

Article: Victoria A. Posey et al.; “Two-dimensional heavy fermions in the van der Waals metal CeSiI”; Nature volume 625, pages 483–488 (2024) , DOI: 10.1038/s41586-023-06868-x, https://www.nature.com/articles/s41586-023-06868-x

For further information:

Chin Shen Ong, researcher at the Department of Physics and Astronomy, Uppsala University, email: chinshen.ong@physics.uu.se